This story is a sequel to Smoothing the Knots
Princesses Celestia and Luna take tea under less than ideal circumstances: house arrest for psychiatric care following Luna's revelation about the her use of the Tantabus to torture herself.
Ever the thoughtful sister, Celestia tries to help Luna open up about her addiction to guilt and suffering in order to understand why Luna isn't happy now that the pain has finally left her. But Luna has a very different topic she wishes to discuss.