Info on DIO

If you were a stand user and you have fight DIO to rescue Celestia, Luna, and Cadance. What are the chances of survival?

First, he can stop time.

Brings down a steam roller on top of you.

Throws a bunch of knives at you.

Also he's a vampire.

If you don't have Stairway to Heaven, Star Platinum or other Post-Stardust Crusaders Stands you will lose. No contest.

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...Fuck it, the princesses are on their own.

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Institute a new government in Equestria because no way in hell am I gonna try and beat that fucker.

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Low to none.

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why the fuck would DIO capture the princesses and not just drink their blood to gain power

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Either lowing their guard so he can plant a flesh bud on them or getting Jotaro and his friends attention.