So Sunset has faced the sirens (RR).

She's faced a plant-related antagonist that caused her friends to forget the most important things (MLtbF).

She's faced a witch/Druid (LoE).

She's faced a cyclops (one-eyed monster/lens) that she had to blind and trick to sneak her and her friends away from (RCoF).

She fled from a goddess offering her immortality/princess-ness (Pre-EG/EG).

And then was trapped in a strange world for 30 moons, for which she kinda blamed Celestia.

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